WebJan 10, 2024 · Flow-induced crystallization of a polyethylene liquid above the melting temperature and its nonequilibrium phase diagram. January 2024; Physical Review Research 2(1) WebJan 19, 2024 · In this work, the flow-induced crystallization of two polylactides (PLAs) with different microstructures (different l-lactic acid contents) is studied using simple shear, uniaxial extension and capillary flow experiments.In a simple shear and capillary flow, an increase in shear rate and a decrease in temperature were found to enhance the …
Modeling Flow-Induced Crystallization SpringerLink
WebBased on classical nucleation theory, the current entropic reduction model (ERM) of flow-induced crystallization (FIC) treats external work as perturbation on the framework of equilibrium thermodynamics, which, however, obscures the nonequilibrium nature of FIC. In this work, in situ investigation on FIC under strong flow by combining a unique … WebFlow-induced nucleation and crystallization are observed in conjugated small molecules and polymers, and are closely related to the flow-induced polymer conformational changes and enhanced mass and heat transfer observed during crystallization. saint marks primary school
Atomistic Simulation of Flow-Induced Microphase Separation and ...
WebNov 7, 2013 · The general phenomenon of shear-induced crystallization (SIC), or flow-induced crystallization (FIC) has been studied extensively, both theoretically and experimentally, for a wide range of ... WebJan 1, 2016 · A modeling framework was presented to describe flow-induced crystallization of iPP at elevated pressures in multiple crystal phases and morphologies. The framework was constructed by … WebFeb 18, 2024 · The effects induced by the flow on polymer crystallization behavior can be summarized into three aspects, namely accelerated nucleation rate, modified crystal morphology, and newly formed crystal structure, which are all directly relevant to the end-use properties [11, 19].To attain the ultimate goal of predicting the polymer … saint marks place institute for mental health